The structure and dielectric properties of BaO-TiO
2
-Nd
2
O
3
(BTN) ceramics are studied. Doping with appropriate amount of glass and additives in the system
a series of temperature compensating monolithic capacitor ceramic (MLC) is obtained at intermediate firing temperature. The experimental results prove that the Curie temperature (T
c
) of BTN ceramics shows a gradual shift with the increasing of Nd
2
O
3
when Ti/Ba=1.003. The micrographs taken by SEM show that the grain size depends on Nd ̄(3+) content. The influence of Ti/Ba ratio on the temperature coefficient of permittivity (α
ε
) of the ceramic has been investigated. The permittivity (α
ε
) and(ε) of BTN system can be adjusted both by changing the Nd
2
O
3
content and Ti/Ba ratio. Moreover
the influences of CaTiO
3
on the electrical properties of BTN are also analyzed.