Research on Gas Sensing Performance and Application of TMA Sensor Based on GaN/Ti3C2Tx

HAN Dan; HONG Yu-tao; LIU Zhi-hua; DUAN Qi; LI Dong-hui; WANG Yu; SHI Jie-xu; SANG Sheng-bo

doi:10.12263/DZXB.20231180

您当前的位置：

首页 >

文章列表页 >

Research on Gas Sensing Performance and Application of TMA Sensor Based on GaN/Ti₃C₂T_x

PAPERS | 更新时间：2025-12-08

- Research on Gas Sensing Performance and Application of TMA Sensor Based on GaN/Ti₃C₂T_x
- ACTA ELECTRONICA SINICA Vol. 52, Issue 4, Pages: 1389-1398(2024)
- 作者机构：
  
  太原理工大学电子信息与光学工程学院，山西太原 030024
- 作者简介：
- 基金信息：
  
  Key Program of the National Natural Science Foundation of China(52375572;62031022);the Key Research and Development Program of Shanxi Province(202102030201003);the Water Resources Department Program of Shanxi Province(2023GM16);Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(2022SX-AT001)
- DOI：10.12263/DZXB.20231180
  CLC： TP212;
- Received：21 December 2023，
  
  Revised：2024-03-07，
  
  Published：25 April 2024
- 稿件说明：
移动端阅览
韩丹, 洪宇涛, 刘志华, 等. 基于GaN/Ti₃C₂T_x的TMA传感器气敏性能及其应用研究[J]. 电子学报, 2024, 52(04): 1389-1398.

HAN Dan, HONG Yu-tao, LIU Zhi-hua, et al. Research on Gas Sensing Performance and Application of TMA Sensor Based on GaN/Ti₃C₂T_x[J]. Acta Electronica Sinica, 2024, 52(04): 1389-1398.
韩丹, 洪宇涛, 刘志华, 等. 基于GaN/Ti₃C₂T_x的TMA传感器气敏性能及其应用研究[J]. 电子学报, 2024, 52(04): 1389-1398. DOI：10.12263/DZXB.20231180

HAN Dan, HONG Yu-tao, LIU Zhi-hua, et al. Research on Gas Sensing Performance and Application of TMA Sensor Based on GaN/Ti₃C₂T_x[J]. Acta Electronica Sinica, 2024, 52(04): 1389-1398. DOI：10.12263/DZXB.20231180

摘要

本文联合溶剂热法和氮化法合成氮化镓（GaN）/Ti

新型复合材料，并研究了基于GaN/Ti

新型复合材料的气体传感器对三甲胺（Trimethylamine，TMA）气体的传感特性.通过一系列表征手段分析了复合材料的形貌以及元素组成特性，证实了GaN与Ti

材料的成功复合.传感器对TMA气体的气敏特性结果表明，GaN/Ti

传感器在室温下能够高效检测1~200 ppm的TMA气体，且与纯GaN传感器相比，对TMA的检测下限由10 ppm降低至1 ppm.此外，复合传感器气敏结果进一步证实了其良好的抗干扰特性以及长期稳定性.利用表面耗尽层模型解释了GaN/Ti

复合传感器气敏机理，及其与纯GaN传感器相比气敏性能提升的原因.最后，本文开发了一种无接触式TMA气体检测装置，检测结果表明该装置有望实现对肝、肾病患者呼出气的高效实时检测，在肝、肾疾病的早期筛查方面具有较大的应用潜力.

Abstract

In this paper

a new type of gallium nitride (GaN) /Ti

composite material was synthesized by solvothermal method and nitriding method

and the sensing characteristics of trimethylamine (TMA) gas sensor based on GaN/Ti

composite were studied. Through a series of characterization methods

the morphology and elemental composition of the composites were analyzed

and the successful composite of GaN and Ti

was confirmed. The results show that GaN/Ti

sensor can efficiently detect 1~200 ppm TMA gas at room temperature

and the detection limit of TMA is reduced from 10 ppm to 1 ppm compared with pure GaN sensor. In addition

the gas sensing results of the composite sensor further confirm its good anti-interference characteristics and long-term stability. The gas-sensitive mechanism of GaN/Ti

composite sensor and the reason of its improved gas-sensitive performance compared with pure GaN sensor are explained by using the surface depletion layer model. Finally

a contactless TMA gas detection device was developed in this paper

d the test results show that the device is expected to achieve efficient real-time detection of exhaled air in patients with liver and kidney disease

and has great application potential in early screening of liver and kidney diseases.

关键词

Keywords

references

MA X F , LI G , WANG M , et al . Oxidative polymerization of pyrrole in the presence of a poly (sodium-p-styrenesulfonate) and its gas-responses [J ] . Journal of Materials Science , 2006 , 41 ( 22 ): 7604 - 7610 .

HANOUNEH I A , ZEIN N N , CIKACH F , et al . The breathprints in patients with liver disease identify novel breath biomarkers in alcoholic hepatitis [J ] . Clinical Gastroenterology and Hepatology , 2014 , 12 ( 3 ): 516 - 523 .

SIMENHOFF M L , BURKE J F , SAUKKONEN J J , et al . Biochemical profile of uremic breath [J ] . The New England Journal of Medicine , 1977 , 297 ( 3 ): 132 - 135 .

WZOREK B , MOCHALSKI P , ŚLIWKA I , et al . Application of GC-MS with a SPME and thermal desorption technique for determination of dimethylamine and trimethylamine in gaseous samples for medical diagnostic purposes [J ] . Journal of Breath Research , 2010 , 4 ( 2 ): 026002 .

ZHANG W H , ZHANG W D . Fabrication of SnO 2 -ZnO nanocomposite sensor for selective sensing of trimethylamine and the freshness of fishes [J ] . Sensors and Actuators B: Chemical , 2008 , 134 ( 2 ): 403 - 408 .

沈佳彬 . 基于Fe 2 O 3 半导体气体传感器对海鲜鱼类中三甲胺快速检测的应用研究 [D ] . 上海 : 上海海洋大学 , 2023 .

ZHAO C , SHEN J B , XU S S , et al . Ultra-efficient trimethylamine gas sensor based on Au nanoparticles sensitized WO 3 nanosheets for rapid assessment of seafood freshness [J ] . Food Chemistry , 2022 , 392 : 133318 .

WANG Y N , ZHANG S D , HUANG C Z , et al . Mesoporous WO 3 modified by Au nanoparticles for enhanced trimethylamine gas sensing properties [J ] . Dalton Transactions , 2021 , 50 ( 3 ): 970 - 978 .

LI Z , ZHANG D Z , WANG X W , et al . Passive and wireless NFC tag-type trimethylamine gas detection based on WO 3 /MXene composite sensors [J ] . Journal of Alloys and Compounds , 2023 , 939 : 168730 .

TIAN W C , LIU X H , YU W B . Research progress of gas sensor based on graphene and its derivatives: A review [J ] . Applied Sciences , 2018 , 8 ( 7 ): 1118 .

ZHOU Y , WANG Y H , WANG Y J , et al . MXene Ti 3 C 2 T x -derived nitrogen-functionalized heterophase TiO 2 homojunctions for room-temperature trace ammonia gas sensing [J ] . ACS Applied Materials & Interfaces , 2021 , 13 ( 47 ): 56485 - 56497 .

LIU L L , SANG S B , HAN D , et al . PEI/PEG functionalized Black Phosphorus prepared by a One-Pot method for a wide detection range CO 2 gas sensor [J ] . Sensors and Actuators B: Chemical , 2022 , 369 : 132303 .

HAN D , HAN X M , LIU L L , et al . Sub-ppb-level detection of nitrogen dioxide based on high-quality black phosphorus [J ] . ACS Applied Materials & Interfaces , 2022 , 14 ( 11 ): 13942 - 13951 .

KIM S J , KOH H J , REN C E , et al . Metallic Ti 3 C 2 T x MXene gas sensors with ultrahigh signal-to-noise ratio [J ] . ACS Nano , 2018 , 12 ( 2 ): 986 - 993 .

WU M , AN Y P , YANG R , et al . V2CTx and Ti 3 C 2 T x MXenes nanosheets for gas sensing [J ] . ACS Applied Nano Materials , 2021 , 4 ( 6 ): 6257 - 6268 .

LIU L K , FU S , LV X , et al . A gas sensor with Fe 2 O 3 nanospheres based on trimethylamine detection for the rapid assessment of spoilage degree in fish [J ] . Frontiers in Bioengineering and Biotechnology , 2020 , 8 : 567584 .

LIU M , JI J , SONG P , et al . Sensing performance of α-Fe 2 O 3 /Ti 3 C 2 Tx MXene nanocomposites to NH 3 at room temperature [J ] . Journal of Alloys and Compounds , 2022 , 898 : 162812 .

LIU M , WANG J X , SONG P , et al . Metal-organic framewor ks-derived In 2 O 3 microtubes/Ti 3 C 2 T x MXene composites for NH 3 detection at room temperature [J ] . Sensors and Actuators B: Chemical , 2022 , 361 : 131755 .

BOUTROS K , CHU R M , HUGHES B . Recent advances in GaN power electronics [C ] // Proceedings of the IEEE 2013 Custom Integrated Circuits Conference . Piscataway : IEEE , 2013 : 1 - 4 .

ZHANG M X , ZHAO C H , GONG H M , et al . Porous GaN submicron rods for gas sensor with high sensitivity and excellent stability at high temperature [J ] . ACS Applied Materials & Interfaces , 2019 , 11 ( 36 ): 33124 - 33131 .

REDDEPPA M , KIMPHUNG N T , MURALI G , et al . Interaction activated interfacial charge transfer in 2D g-C 3 N 4 /GaN nanorods heterostructure for self-powered UV photodetector and room temperature NO 2 gas sensor at ppb level [J ] . Sensors and Actuators B: Chemical , 2021 , 329 : 129175 .

黄大朋 . MXenes材料制备及其随机激光性能研究 [D ] . 济南 : 山东大学 , 2020 .

HUANG D P . Study on Preparation and Random Laser Properties of MXenes Materials [D ] . Jinan : Shandong University , 2020 . (in Chinese)

LI D H , HAN D , CHEN Y , et al . Hollow porous GaN nanofibers gas sensor for superior stability and sub-ppb-level NO 2 gas detection [J ] . Sensors and Actuators B: Chemical , 2022 , 371 : 132583 .

WEI H W , DONG J D , FANG X J , et al . Ti 3 C 2 T x MXene/polyaniline (PANI) sandwich intercalation structure composites constructed for microwave absorption [J ] . Composites Science and Technology , 2019 , 169 : 52 - 59 .

RAJAVEL K , LUO S B , WAN Y J , et al . 2D Ti 3 C 2 T x MXene/polyvinylidene fluoride (PVDF) nanocomposites for attenuation of electromagnetic radiation with excellent heat dissipation [J ] . Composites Part A: Applied Science and Manufacturing , 2020 , 129 : 105693 .

SHARMA A , VARSHNEY M , SARASWAT H , et al . Nano-structured phases of gallium oxide (GaOOH, α-Ga 2 O 3 , β-Ga 2 O 3 , γ-Ga 2 O 3 , δ-Ga 2 O 3 , and ε-Ga 2 O 3 ): Fabrication, structural, and electronic structure investigations [J ] . International Nano Letters , 2020 , 10 ( 1 ): 71 - 79 .

HAN D , CHEN Y , LI D H , et al . Conductometric nitrogen dioxide gas sensor based on gallium nitride quantum dots film [J ] . Sensors and Actuators B: Chemical , 2023 , 379 : 133197 .

MA J W , FAN H Q , LI Z X , et al . Multi-walled carbon nanotubes/polyaniline on the ethylenediamine modified polyethylene terephthalate fibers for a flexible room temperature ammonia gas sensor with high responses [J ] . Sensors and Actuators B: Chemical , 2021 , 334 : 129677 .

RODRIGUES J , SHIMPI N G . Detection of trimethylamine (TMA) gas using mixed shape cobalt doped ZnO nanostructure [J ] . Materials Chemistry and Physics , 2023 , 305 : 127972 .

RAVIKUMAR T , THIRUMALAISAMY L , MADANAGURUSAMY S , et al . Manganese doped two-dimensional zinc ferrite thin films as chemiresistive trimethylamine gas sensors [J ] . Physical Chemistry Chemical Physics , 2023 , 25 ( 46 ): 32216 - 32233 .

REDDEPPA M , MITTA S B , CHANDRAKALAVATHI T , et al . Solution-processed Au@rGO/GaN nanorods hybrid-structure for self-powered UV, visible photodetector and CO gas sensors [J ] . Current Applied Physics , 2019 , 19 ( 8 ): 938 - 945 .

MIAO J W , FAN Y B , ZHU S W , et al . Oxygen vacancies rich in indium oxide hollow prism-like nanoflowers derived from NH 2 -MIL-68 (In) for promoted triethylamine sensing [J ] . Sensors and Actuators B: Chemical , 2024 , 402 : 135109 .

LEE S W , LEE W , HONG Y , et al . Recent advances in carbon material-based NO 2 gas sensors [J ] . Sensors and Actuators B: Chemical , 2018 , 255 : 1788 - 1804 .

MA Z R , SONG P , YANG Z X , et al . Trimethylamine detection of 3D rGO/mesoporous In 2 O 3 nanocomposites at room temperature [J ] . Applied Surface Science , 2019 , 465 : 625 - 634 .

MA L T , FAN H Q , TIAN H L , et al . The n-ZnO/n-In 2 O 3 heterojunction formed by a surface-modification and their potential barrier-control in methanal gas sensing [J ] . Sensors and Actuators B: Chemical , 2016 , 222 : 508 - 516 .

WANG Z J , LI Z Y , SUN J H , et al . Improved hydrogen monitoring properties based on p-NiO/n-SnO 2 heterojunction composite nanofibers [J ] . The Journal of Physical Chemistry C , 2010 , 114 ( 13 ): 6100 - 6105 .

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress on Integrated Triboelectric Self-Powered Gas and Humidity Sensors

Study on a Novel Gas Sensor

Related Author

DUAN Zai-hua

TAI Hui-ling

JIANG Ya-dong

YUAN Zhen

XIE Guang-zhong

LIU Bo-hao

PAN Wei

LI Yan-rong

Related Institution

School of Optoelectronic Science and Engineering， State Key Laboratory of Electronic Thin Films and Integrated Devices， University of Electronic Science and Technology of China

Tsinghua University

University of Electronic Science and Technology of China

Shandong University

Tsinghua UniversityBeijing 100084China

⁰