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1.西安电子科技大学集成电路学部,陕西西安 710071
2.宽禁带半导体器件与集成技术全国重点实验室,陕西西安 710071
3.湖北九峰山实验室,湖北武汉 430074
Received:17 July 2024,
Revised:2024-09-05,
Published:25 December 2024
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许钪, 许晟瑞, 陶鸿昌, 等. Si衬底上基于诱导成核技术的高质量GaN外延[J]. 电子学报, 2024, 52(12): 3907-3913.
XU Kang, XU Sheng-rui, TAO Hong-chang, et al. High Quality GaN Epitaxy Based on Induced Nucleation Technology on Si Substrate[J]. Acta Electronica Sinica, 2024, 52(12): 3907-3913.
许钪, 许晟瑞, 陶鸿昌, 等. Si衬底上基于诱导成核技术的高质量GaN外延[J]. 电子学报, 2024, 52(12): 3907-3913. DOI:10.12263/DZXB.20240662
XU Kang, XU Sheng-rui, TAO Hong-chang, et al. High Quality GaN Epitaxy Based on Induced Nucleation Technology on Si Substrate[J]. Acta Electronica Sinica, 2024, 52(12): 3907-3913. DOI:10.12263/DZXB.20240662
氮化镓(GaN)具有直接带隙、高频、大功率和高电子迁移率等优良的材料特性,使其在电力电子和光电器件等领域都具有广阔的应用前景.Si衬底具备大尺寸、低成本和工艺兼容性好等优势,所以Si基GaN具有很高的研究价值和商业价值.GaN材料的晶体质量决定着GaN基器件的性能,但Si基GaN的晶体质量较差,为此研究人员提出了多种方法来提高GaN的晶体质量,但都存在工艺复杂或成本高昂等问题.因此,本研究提出一种工艺简单且成本低的诱导成核技术来获取高质量的Si基GaN材料.对Si衬底完成相同剂量的N离子注入后进行不同时间的快速热退火处理,使用金属有机化学气相沉积法进行外延生长.结果表明,退火时间为6 min的样品具有最好的晶体质量,表面形貌和光学性能,与对照样品相比,螺位错密度降低14.7%,刃位错密度降低34.4%,总位错密度降低26.1%,并且提高了AlGaN/GaN异质结界面处的二维电子气面密度和电子迁移率,提高了AlGaN/GaN异质结的电学性能.
GaN has excellent material properties such as direct bandgap
high frequency
high power
and high electron mobility
making them have broad application prospects in fields such as power electronic devices and optoelectronic devices. Si substrates have advantages such as large size
low cost
and good process compatibility
so the GaN-on-Si has high research and commercial value. The crystal quality of GaN materials determines the performance of GaN based devices
but the crystal quality of GaN-on-Si is poor. So
researchers have proposed various methods to improve the crystal quality of GaN
but all of them have problems such as complex processes or high costs. Therefore
this research proposes a simple and low-cost induced nucleation technique to obtain high-quality Si based GaN materials. After completing the same dose of N ion implantation on Si substrate
rapid thermal annealing (RTA) treatment was carried out for different times
and epitaxial growth was carried out using metal organic chemical vapor deposition (MOCVD) method. The results showed that the sample with an annealing time of 6 minutes had the best crystal quality
surface morphology
and optical performance. Compared with the control sample
the screw dislocation density decreased by 14.7%
the edge dislocation density decreased by 34.4%
the total dislocation density decreased by 26.1%
and the two-dimensional electron gas (2DEG) surface density and electron mobility at the AlGaN/GaN heterojunction interface were improved
which improved the electrical performance of the AlGaN/GaN heterojunction.
WENG Y C , HSU H T , TSAO Y F , et al . Effects on RF performance for AlGaN/GaN HEMT on Si substrate with AlGaN buffer engineering [J ] . ECS Journal of Solid State Science and Technology , 2023 , 12 ( 3 ): 035002 .
LI G Q , WANG W L , YANG W J , et al . GaN-based light-emitting diodes on various substrates: A critical review [J ] . Reports on Progress in Physics. Physical Society (Great Britain) , 2016 , 79 ( 5 ): 056501 .
杨燕 , 王平 , 郝跃 , 等 . AlGaN/GaN高电子迁移率晶体管解析模型 [J ] . 电子学报 , 2005 , 33 ( 2 ): 205 - 208 .
YANG Y , WANG P , HAO Y , et al . Analytical model for AlGaN/GaN high electron mobility transistor [J ] . Acta Electronica Sinica , 2005 , 33 ( 2 ): 205 - 208 . (in Chinese)
SU H K , XU S R , TAO H C , et al . Improving the current spreading by Fe doping in n-GaN layer for GaN-based ultraviolet light-emitting diodes [J ] . IEEE Electron Device Letters , 2021 , 42 ( 9 ): 1346 - 1349 .
邵国键 , 林罡 , 白霖 , 等 . 帽层结构对GaN HEMT器件性能的影响 [J ] . 固体电子学研究与进展 , 2020 , 40 ( 6 ): 466 - 470 .
SHAO G J , LIN G , BAI L , et al . Effect of cap layer structure on the performance of GaN HEMT device [J ] . Research & Progress of SSE , 2020 , 40 ( 6 ): 466 - 470 . (in Chinese)
MENEGHINI M , DE SANTI C , ABID I , et al . GaN-based power devices: Physics, reliability, and perspectives [J ] . Journal of Applied Physics , 2021 , 130 ( 18 ): 181101 .
WANG Z M , YU G H , YUAN X , et al . Low leakage current in isolated AlGaN/GaN heterostructure on Si substrate by N ion implantation performed at an elevated temperature [J ] . Applied Physics Letters , 2023 , 122 ( 6 ): 062105 .
WU Y F , SAXLER A , MOORE M , et al . 30-W/mm GaN HEMTs by field plate optimization [J ] . IEEE Electron Device Letters , 2004 , 25 ( 3 ): 117 - 119 .
NANJO T , TAKEUCHI M , IMAI A , et al . AlGaN channel HEMT with extremely high breakdown voltage [J ] . MRS Online Proceedings Library , 2011 , 1324 ( 1 ): 1101 .
季启政 , 刘峻 , 杨铭 , 等 . 栅宽对AlGaN/GaN HEMTs亚阈值摆幅的影响 [J ] . 电子学报 , 2023 , 51 ( 6 ): 1486 - 1492 .
JI Q Z , LIU J , YANG M , et al . Gate width influence on subthreshold swing of AlGaN/GaN HEMTs [J ] . Acta Electronica Sinica , 2023 , 51 ( 6 ): 1486 - 1492 . (in Chinese)
YAMASAKI T , KITTAKA Y , MINAMIDE H , et al . A 68% efficiency, C-band 100 W GaN power amplifier for space applications [C ] // 2010 IEEE MTT-S International Microwave Symposium . Piscataway : IEEE , 2010 : 1384 - 1387 .
YAMANAKA K , MORI K , IYOMASA K , et al . C-band GaN HEMT power amplifier with 220 W output power [C ] // 2007 IEEE/MTT-S International Microwave Symposium . Piscataway : IEEE , 2007 : 1251 - 1254 .
GAO Y , XU S R , PENG R S , et al . Comparative research of GaN growth mechanisms on patterned sapphire substrates with sputtered AlON nucleation layers [J ] . Materials , 2020 , 13 ( 18 ): 3933 .
JIANG H H , LI X J . GaN MSM structure UV photodetector detector based on nonplanar Si substrate and its performance optimization [J ] . Semiconductor Science and Technology , 2022 , 37 ( 10 ): 105020 .
WANG K , LI M D , YANG Z J , et al . Stress control and dislocation reduction in the initial growth of GaN on Si (111) substrates by using a thin GaN transition layer [J ] . CrystEngComm , 2019 , 21 ( 32 ): 4792 - 4797 .
LIN Y H , YANG M J , WANG W L , et al . Quality-enhanced GaN epitaxial films on Si(111) substrates by in situ deposition of SiN on a three-dimensional GaN template [J ] . RSC Advances , 2016 , 6 ( 88 ): 84794 - 84800 .
LEE J H , IM K S . Growth of high quality GaN on Si (111) substrate by using two-step growth method for vertical power devices application [J ] . Crystals , 2021 , 11 ( 3 ): 234 .
YANG X L , SHEN J F , CAI Z D , et al . Effect of carbon impurity on the dislocation climb in epitaxial GaN on Si substrates [J ] . Applied Physics Express , 2022 , 15 ( 10 ): 105501 .
RIAH B , CAMUS J , AYAD A , et al . Hetero-epitaxial growth of AlN deposited by DC magnetron sputtering on Si(111) using a AlN buffer layer [J ] . Coatings , 2021 , 11 ( 9 ): 1063 .
JIN Z Y , GUO L , XIAO L , et al . Epitaxial growth of GaN on porous Si (111) substrate [C ] // 2016 5th International Symposium on Next-Generation Electronics (ISNE) . Piscataway : IEEE , 2016 : 1 - 3 .
TAO H C , XU S R , ZHANG J C , et al . Improved crystal quality and enhanced optical performance of GaN enabled by ion implantation induced high-quality nucleation [J ] . Optics Express , 2023 , 31 ( 13 ): 20850 - 20860 .
GUO L C , WANG X L , WANG C M , et al . The influence of 1 nm AlN interlayer on properties of the Al 0.3 Ga 0.7 N/AlN/GaN HEMT structure [J ] . Microelectronics Journal , 2008 , 39 ( 5 ): 777 - 781 .
WANG W K , JIANG M C . Growth behavior of hexagonal GaN on Si(100) and Si(111) substrates prepared by pulsed laser deposition [J ] . Japanese Journal of Applied Physics , 2016 , 55 ( 9 ): 095503 .
KADIR A , SRIVASTAVA S , LI Z , et al . Influence of substrate nitridation on the threading dislocation density of GaN grown on 200 mm Si (111) substrate [J ] . Thin Solid Films , 2018 , 663 : 73 - 78 .
LIN P J , TIEN C H , WANG T Y , et al . On the role of AlN insertion layer in stress control of GaN on 150-mm Si (111) substrate [J ] . Crystals , 2017 , 7 ( 5 ): 134 .
MORAM M A , VICKERS M E . X-ray diffraction of III-nitrides [J ] . Reports on Progress in Physics , 2009 , 72 ( 3 ): 036502 .
BAN K , YAMAMOTO J I , TAKEDA K , et al . Internal quantum efficiency of whole-composition-range AlGaN multiquantum wells [J ] . Applied Physics Express , 2011 , 4 ( 5 ): 052101 .
冯倩 , 郝跃 , 刘玉龙 . GaN薄膜拉曼散射光谱的研究 [J ] . 光散射学报 , 2003 , 15 ( 3 ): 175 - 178 .
FENG Q , HAO Y , LIU Y L . A study on Raman scattering spectra of GaN film [J ] . Chinese Journal of Light Scattering , 2003 , 15 ( 3 ): 175 - 178 . (in Chinese)
JIANG T , XU S R , ZHANG J C , et al . Spatially resolved and orientation dependent Raman mapping of epitaxial lateral overgrowth nonpolar a-plane GaN on r-plane sapphire [J ] . Scientific Reports , 2016 , 6 : 19955 .
TAO H C , XU S R , SU H K , et al . Improved crystal quality of AlGaN by Al ion-implantation sapphire substrate [J ] . Materials Letters , 2023 , 351 : 135097 .
张金风 , 郝跃 , 张进城 , 等 . 变Al组分AlGaN/GaN结构中的二维电子气迁移率 [J ] . 中国科学(E辑: 信息科学) , 2008 , 38 ( 6 ): 949 - 958 .
ZHANG J F , HAO Y , ZHANG J C , et al . Two-dimension Al electron gas mobility in AlGaN/GaN structure with variable al composition [J ] . Science in China (Series E (Information Sciences)) , 2008 , 38 ( 6 ): 949 - 958 . (in Chinese)
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