It is especially important to preserve some characters of the original system while numerical simulating three-dimensional time domain Maxwell's Equations.The Maxwell's equations are written as normal Hamilton equations using functional variation method.We discretize Maxwell's equations in the time direction using sympletic propagation technique and then evaluate the equations in the spatial direction with high-order nature of spatial multi-resolution approximations to construct symplectic Multi-Resolution Time Domain (S-MRTD) scheme.The stability and numerical dispersion analysis are also included.Numerical results are given to show the high efficiency and accuracy of the S-MRTD scheme.