QI Shi-kai, WANG Xiao-xia, WANG Xing-qi, et al. A Novel Direct-Heated Rare-Earth Gd2Hf2O7 Ceramic Cathode Applied in Magnetron[J]. Acta Electronica Sinica, 2020, 48(11): 2233-2241.
DOI:
QI Shi-kai, WANG Xiao-xia, WANG Xing-qi, et al. A Novel Direct-Heated Rare-Earth Gd2Hf2O7 Ceramic Cathode Applied in Magnetron[J]. Acta Electronica Sinica, 2020, 48(11): 2233-2241. DOI: 10.3969/j.issn.0372-2112.2020.11.020.
A Novel Direct-Heated Rare-Earth Gd2Hf2O7 Ceramic Cathode Applied in Magnetron
ceramic cathode. The thermionic emission and life characteristics of the Gd
2
Hf
2
O
7
cathode had been measured. The results show that the cathode can provide
0.1A/cm
2
current density for the space charge limitation at 1300℃br
more than 1.93A/cm
2
at 1600℃br under 300V anode voltage. The lifetime for the cathode is more than 4000 h with an initial load of 0.5A/cm
2
at 1500℃br. Finally
the molecular structure
surface microstructure
element composition and content of the Gd
2
Hf
2
O
7
ceramic cathode had been analyzed by the XRD
SEM
EDS
AES (equipped with argon ion etching in-depth analysis) respectively. The analysis results show that the single Gd
2
Hf
2
O
7
phase has formed in the high sintering temperature. When the Gd
3+
valences Gd
2
O
3
doped the Hf
4+
valences HfO
2
the substitutional solid solution will be formed. In order to maintain the electrical neutrality of the Gd
2
Hf
2
O
7
lattice
an oxygen vacancy will be generated in the lattice. During the cathode activating
aging
and thermally testing
the oxygen vacancy will be generated fast. The more oxygen vacancies are obtained
the better the conductivity of the cathode surface has. Besides
the work function of the cathode can also be reduced due to the improvement of the electro-conductivity that enhances the thermionic emission capability of the cathode.